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Titlebook: Autoxidation in Food and Biological Systems; Michael G. Simic,Marcus Karel Book 1980 Springer Science+Business Media New York 1980 Oxidati

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期刊全称Autoxidation in Food and Biological Systems
影响因子2023Michael G. Simic,Marcus Karel
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图书封面Titlebook: Autoxidation in Food and Biological Systems;  Michael G. Simic,Marcus Karel Book 1980 Springer Science+Business Media New York 1980 Oxidati
影响因子The material presented in this book deals with basic mechanisms of free radical reactions in autoxidation processes and anitoxidant suppression of autoxidation of foods, biochemical models and biologi­ cal systems. Autoxidation in foods and corresponding biological effects are usually approached separately although recent mechanistic developments in the biochemistry and free radical chemistry of per­ oxides and their precursors tend to bring these two fields closer. Apparent ability of antioxidants in diets to reduce the inci­ dence of cancer has resulted in scrutiny of autoxidized products and their precursors as possibly toxic, mutagenic and carcinogenic agents. Mechanisms of any of these effects have been barely ad­ dressed. Yet we know now that free radicals, as esoteric as they were only a few decades ago, are being discovered in foods, biochem­ ical and biological systems and do play a role in the above-mentioned causalities. The purpose of the Workshop and the resulting book was to give a unifying approach towards study of beneficial and deleterious effects of autoxidation, based on rigorous scientific considerations. It is our hope that the material presented in this book w
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Kinetic and Mechanistic Studies of Peroxy, Vitamin E and Anti-Oxidant Free Radicals by Pulse Radiolyy radicals, RO· and superoxide radical (sometimes also called perhydroxyl radical), ·O.. + H. ⇋ ·O.H. As indicated, the superoxide radical comes in two forms: (a) the anionic form, ·O.., which is present predominantly in solutions with pH above pK. = 4.8, and (b) the protonated form, ·O.H, which is
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Spin Trapping of Radical Species Involved in the Propagation of Lipid Peroxidation are incorporated into the phosphoglycerides of membranes. The peroxidative process has been shown to be a radical chain reactive sequence which has separate initiation, propagation and termination steps.. Initiation is thought to occur either by a radical addition to a double bond or by abstraction
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Dioxygen Complexes as Intermediates in Metal-Catalyzed Oxidation of Organic Substancesates by molecular oxygen in the presence of metal ions may occur through the same mechanism, i.e., by direct oxidation of the organic ligand through an inner sphere electron transfer from the ligandto the metal ion followed by reoxidation of the metal ion in solution by molecular oxygen. In certain
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Rapid Instrumental Analysis of Lipid Oxidation Productssed or further oxidized to secondary products such as alcohols, acids, ketones, and aldehydes that are capable of reacting with other constituents of food such as amino acids, proteins, enzymes, and vitamins. These reactions can have an adverse affect on the nutritive value and quality of their resp
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