Titlebook: Amplification of Chirality; Kenso Soai Book 2008 Springer-Verlag Berlin Heidelberg 2008 Enantiomer.asymmetric catalysis.catalysis.chemistr

使长胖

ambivalence

KIN

Besonderheiten der Axialschaufel, provide furtherinsight into the steric control of autocatalysis by the bulk of diisopropylzinc. NMR, kinetics andcomputation converge in supporting the role of dimers of the indicated structure, and in pointingto a mechanism whereby the unique reactivity of the homochiral dimer is the driving force, atleast at ambient temperature.

整洁

Asymmetric Autocatalysis with Organozinc Complexes; Elucidation of the Reaction Pathway, provide furtherinsight into the steric control of autocatalysis by the bulk of diisopropylzinc. NMR, kinetics andcomputation converge in supporting the role of dimers of the indicated structure, and in pointingto a mechanism whereby the unique reactivity of the homochiral dimer is the driving force, atleast at ambient temperature.

Awning

Asymmetric Autocatalysis with Amplification of Chirality,ith low ee is described. Direct examination of extraterrestrial chirality was performedon meteorites by applying asymmetric autocatalysis as the chiral sensor. Spontaneous absolute asymmetricsynthesis is described in the formation of enantiomerically enriched pyrimidyl alkanol from the reactionof py

Foolproof

Rate Equation Approaches to Amplification of Enantiomeric Excess and Chiral Symmetry Breaking,molecule concentrations. Theee amplification takes place when the flow terminates on a line of fixed points (or a fixed line),whereas symmetry breaking corresponds to the dissolution of the fixed line accompanied by the appearanceof fixed points. The relevance of the Soai reaction to the homochirali

expunge

Indecisive

Lucubrate

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