Titlebook: Alkane C-H Activation by Single-Site Metal Catalysis; Pedro J. Pérez Book 2012 Springer Science+Business Media Dordrecht 2012 Alkane trans

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0920-4652 erspective of the topics discussed to inspire future works o.Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the c

intuition

Book 2012gen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. .Alkane C-H Activation by Single-Site Metal Catal.ysis presents the current state-of-the-art development in the catalytic

inspired

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https://doi.org/10.1007/978-3-319-68913-5esses is discussed. A major focus of this review is on the deployment of so called ‘pincer-ligand’ based catalyst systems for use in transfer dehydrogenations. The development and use of supported pincer catalysts is considered.

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结果

Alkane Catalytic Functionalization by Carbene or Nitrene Insertion Reactions, have been reported for the conversion of plain, non-activated alkanes into value added products. The development of these methodologies, current state of the art, including asymmetric systems and mechanistic considerations are described.

Arresting

Positive Bases and Nonsmooth Optimizationis surveyed here, with particular emphasis on mechanistic understanding, examples of actual functionalization at ..-hybridized C–H bonds in alkanes and related compounds, and assessment of the further development that will be needed for practical applications.

synchronous

Alkane Functionalization via Electrophilic Activation,is surveyed here, with particular emphasis on mechanistic understanding, examples of actual functionalization at ..-hybridized C–H bonds in alkanes and related compounds, and assessment of the further development that will be needed for practical applications.

Suppository

,Introduction: Alkane C–H Activation by Single-Site Metal Catalysis,s a brief history of metal-mediated C–H activation and review of various transformations by which metals induce the cleavage of C–H bonds. An introduction to some of the prominent strategies to develop transition metal catalysts for alkane functionalization is presented.

Constituent