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Titlebook: Alkane C-H Activation by Single-Site Metal Catalysis; Pedro J. Pérez Book 2012 Springer Science+Business Media Dordrecht 2012 Alkane trans

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期刊全称Alkane C-H Activation by Single-Site Metal Catalysis
影响因子2023Pedro J. Pérez
视频videohttp://file.papertrans.cn/154/153378/153378.mp4
发行地址Provides state of the art in the field of catalytic functionalization of alkanes under homogenous conditions.Each chapter concludes with a perspective of the topics discussed to inspire future works o
学科分类Catalysis by Metal Complexes
图书封面Titlebook: Alkane C-H Activation by Single-Site Metal Catalysis;  Pedro J. Pérez Book 2012 Springer Science+Business Media Dordrecht 2012 Alkane trans
影响因子.Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. .Alkane C-H Activation by Single-Site Metal Catal.ysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system.  Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. .The history of C-H bond activation, and the current research descri
Pindex Book 2012
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Positive Bases and Nonsmooth Optimizationhe basis of a number of promising approaches to selective catalytic functionalization of alkanes. The field was introduced by the groundbreaking chemistry exhibited by aqueous chloroplatinum complexes, reported by Shilov in the early 1970s. Since then the field has expanded greatly, and electrophili
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Building Linear and Quadratic Modelsenges to the design of reagents that could enable their selective oxidation. Highly reactive-oxidizing reagents are needed, and this factor poses major problems in terms of chemo and regioselectivity. Despite all these conditionings, because of its technological and biological significance and impli
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,Introduction: Alkane C–H Activation by Single-Site Metal Catalysis,s a brief history of metal-mediated C–H activation and review of various transformations by which metals induce the cleavage of C–H bonds. An introduction to some of the prominent strategies to develop transition metal catalysts for alkane functionalization is presented.
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Alkane C-H Activation by Single-Site Metal Catalysis978-90-481-3698-8Series ISSN 0920-4652 Series E-ISSN 2215-180X
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