Titlebook: Water Structure at the Water-Polymer Interface; Proceedings of a Sym H. H. G. Jellinek Conference proceedings 1972 Plenum Press, New York 1

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Movement of Water in Homogeneous Water-Swollen Polymers,hat are as nearly homogeneous as can experimentally be achieved; these are hydrogels, which offer the added advantage that they can be prepared with widely varying water contents. Transport properties and molecular mobility can therefore be studied in dependence on the degree of hydration, that is t

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Kinetic and Spectral Evidence for Selective Solvation of a Hydrophobic Quinoneimine Dye in Mixed Aqmacromolecules and small ions, whose solvation has been studied extensively. Most of the bulk of a dye molecule is hydrophobic and capable of acting as a “structure-former” in water, although the orientation of water molecules in the hydration sphere may not be as uniform as might be expected for a

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A Model for the Binding of Chain-Like Molecules to Compact Macromolecular Surfaces, use uniform and essentially infinite planar lattices to represent the surface, a restriction which prevents their application to situations in which the binding surface either is limited in size or covers the surface of a compact particle. Examples of the latter case include colloidal particles and

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Effect of State of Condensation on the Ionization Potential of Associated Liquids,have been identified as products of photolysis in liquid water by a number of characteristic reactions using competition kinetics as a quantitative criterion. The reactions e.. + SF., e.. + H.O., and e.. + Cd. have been used as the principal analytical tools of investigation. The photoproduction of

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Solute Interference Effects in Freezing Potentials of Dilute Electrolytes,gnitude and sign of the potential difference depend on concentrations and kinds of solute species. Electrical neutrality is restored by a flux of hydroniums (protons) and hydroxyls, present in solution or generated by electrolysis. Interference effects occur between competing solute species in a fre

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Effect of Solute on Ice-Solution Interfacial Free Energy; Calculation from Measured Homogeneous Nucg ice from solid polymer and ice from aqueous polymer solution. The ice — solid polymer interface has been the subject of considerable attention; it was, for example, discussed at the Sapporo Conference on the Physics of Snow and Ice in 1966 /1/ and was the subject of a symposium chaired by Dr. H. H

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Water Structure at the Water-Polymer Interface,f water on glass surfaces (Lehner, 1927; Smith, 1928). In 1929, deBoer and Zwikker (1929) presented a polarization theory, in which they attributed multilayer condensation to a propagated electrical polarization initiated at the polar solid surface.

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Structured Water and Complexed Na+ and K+ in Biological Systems, accepted because of its conceptual simplicity, not because of experimental evidence for its validity. Adequate experimental tests of the basic hypotheses of this picture have become possible only recently.

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