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Titlebook: Vibrations at Surfaces; R. Caudano,J.-M. Gilles,A. A. Lucas Book 1982 Plenum Press, New York 1982 Absorption.Atom.Chemisorption.Cross sect

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书目名称Vibrations at Surfaces
编辑R. Caudano,J.-M. Gilles,A. A. Lucas
视频video
图书封面Titlebook: Vibrations at Surfaces;  R. Caudano,J.-M. Gilles,A. A. Lucas Book 1982 Plenum Press, New York 1982 Absorption.Atom.Chemisorption.Cross sect
描述This volume contains most of the invited and contributed papers presented at the second international conference devoted to the general topic "Vibrations at Surfaces" and which took place from 10 to 12 September 1980 at the Facu1tes Notre-Dame de 1a Paix in Namur, Belgium. The conference was organized to review the large amount of information gathered in this field over the late seventies as a result of th~ rapid improvements and dissemination of surface spectroscopic technique such a electron energy loss, infrared and Raman surface spectroscopies. Much time was devoted to Raman spectroscopy of adsorbed mo1e­ ‘cu1es. After several years of vivid debate over the causes of the observed large enhancement of Raman cross section, a clearer pic­ ture emerges from the papers presented here: the actual value of the enhancement factor does depend in a complicated manner on long range surface roughness, atomic-scale roughness and the dielectric properties of the substrate as well as on the electronic structure of the molecule in its adsorbed state. Less controversial are the results obtained with electron energy loss spectroscopy (EELS) and several sessions of the con­ ference were devoted t
出版日期Book 1982
关键词Absorption; Atom; Chemisorption; Cross section; Sorption; adsorption; bonding; catalyst; electron energy los
版次1
doihttps://doi.org/10.1007/978-1-4684-4058-4
isbn_softcover978-1-4684-4060-7
isbn_ebook978-1-4684-4058-4
copyrightPlenum Press, New York 1982
The information of publication is updating

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Eels of Surface Phonons and Vibrations of Adsorbed Speciesctrons. The same phonon frequencies are observed after adsorbing H., O., C.H., or NO. Sideband- or multiple excitations including the metal phonons are observed. Examples show that the Ni-surface phonons can be excited by both dipole and impact scattering. Implications of these results for the inter
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rface roughness, atomic-scale roughness and the dielectric properties of the substrate as well as on the electronic structure of the molecule in its adsorbed state. Less controversial are the results obtained with electron energy loss spectroscopy (EELS) and several sessions of the con­ ference were devoted t978-1-4684-4060-7978-1-4684-4058-4
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Vibrational Lifetimes for Molecules Adsorbed on Metal SurfacesTheoretical calculations of the decay of vibrations of molecules adsorbed on a metal surface due to excitation of electronhole pairs in the metal are described and discussed. Both a dipole- and a resonance-coupling model are considered. Calculated lifetimes are compared with the measured value for the system CO/Cu(100).
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https://doi.org/10.1007/978-1-4684-4058-4Absorption; Atom; Chemisorption; Cross section; Sorption; adsorption; bonding; catalyst; electron energy los
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