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Titlebook: United States-Japan Seminar on Host-Guest Chemistry; Proceedings of the U George W. Gokel,Kenji Koga Conference proceedings 1989 Kluwer Aca

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Iwao Tabushi (1933–1987)her remarkable man impressed me so strongly by his qualities as a human being, and by the way that he addressed his professional interests that I feel moved to add my own testimony to that made by others in commemorating him.
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Progress Toward Artificial Metalloenzymes: New Ligands for Transition Metal Ions and Neutral Molecul molecular recognition system, new molecular receptors for organic substrates have been investigated. The receptors are constructed from two subunits of cholic acid and display amphophilic character — a hydrophobic exterior and a hydrophilic interior. Conformational properties in the presence of polar guests in CDC1. are described.
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New Molecular Shapes for Recognition and Catalysis. The sizes and shapes of the clefts are controlled by the use of appropriate spacer elements. The selective binding of acids, amines, amino acids, metal ions, heterocyclic compounds and nucleosides is described. Their special applicability to problems involving concerted catalysis is also introduced.
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Molecular Recognition of Hydrophobic Ammonium Substrates by a Cationic Octopus Cyclophane Bearing No complexation process. The cyclophane acted as an effective apoenzyme model for constitution of an artificial vitamin B. dependent holoenzyme by simultaneous incorporation of pyridoxal-5’-phosphate and a hydrophobic alkylammonium substrate into the host cavity to give the Schiff-base species, showing the substrate selectivity.
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Molecular Recognition and Host-Guest Interactions in Complexes of O-Bistren, C-Bistren, and Bisdien reported. The ability of the dicobalt(II)-BISDIEN complex to coordinate dioxygen and an additional bifunctional guest simultaneously, leads to the possibility of a new type of catalysis occurring within the cavity of a macrocyclic complex.
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Studies Directed Toward the Fabrication of a Synthetic Cation-conducting Channel Based on Lariat Ethnce. Second, we have prepared three .(macrocyclic) systems that are simplified versions of the proposed channel-former. Third, we have demonstrated the strength of carefully-conceived hydrogen bonding interactions by constructing a molecular box based on the interaction between adenine and thymine.
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The Interactions of Surfactant Viologens with Cyclodextrinsrization of the viologen cation radicals is essentially suppressed by the presence of .-cyclodextrin (ACD) while no effects are observed in the presence of .-cyclodextrin (BCD). The observed results are best explained by the relative solubility in aqueous media of each of the inclusion complexes in the several accessible viologen oxidation states.
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