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Titlebook: Understanding Luminescence Spectra and Efficiency Using Wp and Related Functions; Charles W. Struck,William H. Fonger Book 1991 Springer-V

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书目名称Understanding Luminescence Spectra and Efficiency Using Wp and Related Functions
编辑Charles W. Struck,William H. Fonger
视频video
丛书名称Inorganic Chemistry Concepts
图书封面Titlebook: Understanding Luminescence Spectra and Efficiency Using Wp and Related Functions;  Charles W. Struck,William H. Fonger Book 1991 Springer-V
描述There are both a remote and a proximate history in the development of this book. We would like to acknowledge first the perceptiveness of the technical administrators at RCA Laboratories, Inc. during the 1970s, and in particular Dr. P. N. Yocom. Buoyed up by the financial importance of yttrium oxysulfide: europium as the red phosphor of color television tubes, they allowed us almost a decade of close cooperation aimed at understanding the performance of this phosphor. It is significant that we shared an approach to research in an industrial laboratory which allowed us to avoid the lure of "first-principles" approaches (which would have been severely premature) and freed us to formulate and to study the important issues directly. We searched for a semiquantitative understanding of the properties observed in luminescence, i. e. , where energy absorption occurs, where emission occurs, and with what efficiency this conversion process takes place. We were aware that the nonradi­ ative transition rates found in practice vary enormously with temperature and, for a given activator, with small changes in its environment. We traced the source of this enormous variation to the magnitude of th
出版日期Book 1991
关键词Absorption; Lumineszenz; Strahlungsloser Übergang; luminescence; spectra
版次1
doihttps://doi.org/10.1007/978-3-642-48629-6
isbn_softcover978-3-642-48631-9
isbn_ebook978-3-642-48629-6Series ISSN 0172-7966
issn_series 0172-7966
copyrightSpringer-Verlag Berlin Heidelberg 1991
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Introduction,. The word “center” implies that the most important observed properties can be understood while restricting one’s attention to a particular lattice site and its immediate surroundings. Free excitonic absorption and emission, for example, are beyond the scope of a model of a luminescence “center”, be
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Representative Luminescence Centers,ission spectra both with equal and with unequal force constants. Such descriptions might keep the sum of the first moments and the product of the second moments constant, i.e., using the first two of Eqs. (4.109) and (4.112) truncated to only their first terms and evaluated at 0 K, would have
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Experimental Studies, not shown. They are split into seven . states spanning about 6 000 cm. with . between 0 and 6. They would be placed with the zero of energy at the minimum of the .F. parabola and with only minor offsets, with . < 100 cm.. The first set of excited 4. states are the .D states, split into five . state
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Introduction,te and its immediate surroundings. Free excitonic absorption and emission, for example, are beyond the scope of a model of a luminescence “center”, because the nature of these optical processes involves the whole lattice. But for the large majority of observed luminescent materials, the “center” is a useful concept.
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