书目名称 | Two Studies in Gas-Phase Ion Spectroscopy |
副标题 | Vacuum-Ultraviolet N |
编辑 | Matthew J. Simpson |
视频video | |
概述 | Nominated by the University of Birmingham for a Springer Theses Prize..From a huge quantity of data the author attempts to rationalise the circumstances needed for favourable formation of anions.The m |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | In this thesis Matthew Simpson reportstwo areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules. The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals. |
出版日期 | Book 2012 |
关键词 | Bimolecular Ion Molecule kinetics; Cation anion thermochemistry; Dissociative electron attachment; Ion- |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-642-23129-2 |
isbn_softcover | 978-3-642-27127-4 |
isbn_ebook | 978-3-642-23129-2Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer-Verlag Berlin Heidelberg 2012 |