| 书目名称 | Transport, Relaxation, and Kinetic Processes in Electrolyte Solutions | | 编辑 | Pierre Turq,Josef M. G. Barthel,Marius Chemla | | 视频video | | | 丛书名称 | Lecture Notes in Chemistry | | 图书封面 |  | | 描述 | The presence of freely moving charges gives peculiar properties to electrolyte solutions, such as electric conductance, charge transfer, and junction potentials in electrochemical systems. These charges play a dominant role in transport processes, by contrast with classical equilibrium thermodynamics which considers the electrically neutral electrolyte compounds. The present status of transport theory does not permit a first prin ciples analys1s of all transport phenomena with a detailed model of the relevant interactions. Host of the models are still unsufficient for real systems of reasonable complexity. The Liouville equation may be adapted with some Brownian approximations to problems of interact ing solute particles in a continuum (solvent>; however, keeping the Liouville level beyond the limiting laws is an unsolvable task. Some progress was made at the Pokker-Planck level; however, despite a promising start, this theory in its actual form is still unsatis factory for complex systems involving many ions and chemical reac tions. A better approach is provided by the so-called Smoluchowski level in which average velocities are used, but there the hydrodyna mic interactions | | 出版日期 | Book 1992 | | 关键词 | Diffusion; Electrolyt; Ion; Ionentransport; Migration; Physikalische Chemie; chemical reaction; electrochem | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-642-48755-2 | | isbn_softcover | 978-3-540-55002-0 | | isbn_ebook | 978-3-642-48755-2Series ISSN 0342-4901 Series E-ISSN 2192-6603 | | issn_series | 0342-4901 | | copyright | Springer-Verlag Berlin Heidelberg 1992 |
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