书目名称 | Total Synthesis of (±)-Maoecrystal V |
编辑 | Jianxian Gong |
视频video | |
概述 | Nominated by Peking University as an outstanding PhD thesis.Comprehensively introduces the model study of Maoecrystal V.Describes the first successful total synthesis of Maoecrystal V in detail.Includ |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | .In this thesis, the author describes the total synthesis of natural product Maoecrystal V in detail. In the first part of the thesis, the author introduces the research background and reviews the research progress in total synthesis of Maoecrystal V. In the second part, the author develops a novel and concise approach for the stereo selective construction of the tetracyclic model system of Maoecrystal V. The model system is accomplished in 8 steps with 20% yield. In the third part, the author describes the first successful total synthesis of Maoecrystal V and investigates four strategies for constructing the key tetrahydrofuran oxa-bridge skeleton. The total synthesis starts from a known compound and is accomplished in 17 steps with 1.2% yield. The successful total synthesis of Maoecrystal V will contribute to the development of efficient synthetic strategies for natural products and other compounds with complex structures.. |
出版日期 | Book 2014 |
关键词 | Intramolecular Diels-Alder Reaction; Maoecrystal V; Natural Product; Pinhey Arylation; Stereoselective; T |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-642-54304-3 |
isbn_softcover | 978-3-662-51289-0 |
isbn_ebook | 978-3-642-54304-3Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer-Verlag Berlin Heidelberg 2014 |