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Titlebook: Topics In Organic Polarography; P Zuman Book 1970 Plenum Publishing Company Ltd. 1970 Sorption.adsorption.aldehyde.amines.carboxylic acid.

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Desorption of 3-Phenylpropionaldehyde preceding Polarographic Reduction the interpretation of polarographic measurements, it is usually assumed that organic compounds are only reduced when they are adsorbed onto the surface of the mercury electrode.. Unfortunately, the term “adsorption” is used for a broad range of interactions between the solid and liquid phase.
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Polarographic Behaviour of ,-Diacetylbenzene; An Example of a Compound with Two Electroactive CentersOrganic compounds bearing two electroactive centers (R., R.) in their molecule (R.-A-R.) can be divided, according to their polarographic behaviour, principally into three groups.
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Fission of Activated Carbon-Nitrogen and Carbon-Sulfur Bonds. IX. Polarographic Study of Addition of Primary Amines to Phenyl Vinyl KetoneFree base form of primary amines is added in a reversible reaction to phenyl vinyl ketone. Kinetics verified the scheme (.)—(.). Alkyl groups R in RNH. exert considerable steric effects on this reaction. The nucleophilic reactivity of amines in this reaction parallels the reactivity in other nucleophilic reactions of amines.
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Introductionrocesses involved. Often, suggested reaction schemes were deduced only from a knowledge of the initial and final compositions of the electrolysed solution. Polarography has contributed more to the understanding of processes involved in the electrolysis of organic substances, than any other method.
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