| 书目名称 | The Synergy Between Dynamics and Reactivity at Clusters and Surfaces |
| 编辑 | Louis J. Farrugia |
| 视频video | |
| 丛书名称 | Nato Science Series C: |
| 图书封面 |  |
| 描述 | The analogy between the chemistry of molecular transition metalclusters and the processes of chemisorption and catalysis at metalsurfaces (the .Cluster Surface. analogy) has for a number of yearsprovided an interplay between experimental and theoretical inorganicand physical chemists. This collaborative approach has born fruit inthe use of well defined modes of metal-ligand bonding indiscrete molecular clusters, models for metal-ligand binding onsurfaces. Some of the key topics discussed in .The Synergybetween. .Dynamics and Reactivity at Clusters and Surfaces. are:(1) Mechanisms of the fluxional behaviour in clusters in the liquidphase and the connections with diffusion processes on extendedsurfaces. The role of metal-metal bond breaking in diffusion.(2) Analogies in the structure of chemisorbed species and relatedligands on metallic clusters. (3) Analogies between benzene surfacechemistry on extended metal surfaces and on metal surfaces inmolecular cluster compounds with particular reference to structuraldistortions. (4) The role of mobile precursors for dissociation ofchemisorption on extended metals and on clusters. Are there analogiesin the ligand attachment during cluster com |
| 出版日期 | Book 1995 |
| 关键词 | Osmium; Rhenium; Ruthenium; adsorption; bonding; carbon; catalysis; gold; metals; nickel; platinum; silver; ster |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-94-011-0133-2 |
| isbn_softcover | 978-94-010-4060-0 |
| isbn_ebook | 978-94-011-0133-2Series ISSN 1389-2185 |
| issn_series | 1389-2185 |
| copyright | Springer Science+Business Media Dordrecht 1995 |
发表于 2025-3-21 18:30:47
