| 书目名称 | Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato | | 编辑 | Priyabrata Ghana | | 视频video | | | 概述 | Nominated as an outstanding Ph.D. thesis by the Rheinische Friedrich-Wilhelms-Universität Bonn, Germany.Shows how open-shell tetrylidyne complexes can be made from closedshell tetrylidyne complexes.Ou | | 丛书名称 | Springer Theses | | 图书封面 |  | | 描述 | .This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. .The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si–Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts, open-shell tetrylidyne complexes and heavier group 14 element congeners of metallacarbynes and carbide complexes remained inaccessible. .In this book, readers will find more about the synthesis, full characterization and reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated | | 出版日期 | Book 2019 | | 关键词 | Heavy tetrel elements (Si-Pb); Open-Shell Tetrylidyne Complexes; Heavier Analogue of Alkylidyne Comple | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-030-02625-7 | | isbn_ebook | 978-3-030-02625-7Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | Springer Nature Switzerland AG 2019 |
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书目名称Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato影响因子(影响力)
书目名称Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato影响因子(影响力)学科排名
书目名称Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato网络公开度
书目名称Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato网络公开度学科排名
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发表于 2025-3-21 19:31:54
