书目名称 | Symmetry in Inorganic and Coordination Compounds |
副标题 | A Student‘s Guide to |
编辑 | Franca Morazzoni |
视频video | |
概述 | Describes and compares chemical bonding in inorganic and coordination compounds using variation and perturbation methods.Shows how general symmetry rules can describe the chemical bond of even simple |
丛书名称 | Lecture Notes in Chemistry |
图书封面 |  |
描述 | .This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels..Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.. |
出版日期 | Book 2021 |
关键词 | Chemical Bond Symmetry Rules; Bond-Symmetry Relationships; Crystal and Ligand Field Approach; Structure |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-030-62996-0 |
isbn_softcover | 978-3-030-62998-4 |
isbn_ebook | 978-3-030-62996-0Series ISSN 0342-4901 Series E-ISSN 2192-6603 |
issn_series | 0342-4901 |
copyright | Springer Nature Switzerland AG 2021 |