| 书目名称 | Symmetry Properties of Molecules |
| 编辑 | G. S. Ezra |
| 视频video | http://file.papertrans.cn/884/883962/883962.mp4 |
| 丛书名称 | Lecture Notes in Chemistry |
| 图书封面 |  |
| 描述 | The aIm of the present article is to give a critical exposition of the theory of the symmetry properties of rigid and nonrigid molecules. Despite the fact that several accounts of the subject, both technical and didactic, are now available, and despite the extensive discussion of nonrigid molecule symmetry that has been going on since the classic papers of Hougen and Longuet-Higgins, there remains a need for a unifying survey of the problem. Previous treatments have tended to emphasize one or the other particular viewpoint at the expense of a broader view. Renewed interest in the details of the symmetry classification of rotation vibration states of highly symmetric (octahedral) molecules has led to a reexam ination of the relation between conventional point group operations and permutations of identical nuclei in rigid molecules, together with a clarification of the fundamental role of the Eckart constraints and associated Eckart frame. As is shown below, analogous insights can also be obtained in the case of nonrigid molecule symmetry, where the Eckart-Sayvetz conditions provide a natural generalization of the Eckart constraints. The importance of particular definitions of the |
| 出版日期 | Textbook 1982 |
| 关键词 | Molecules; Molekül; Properties; Symmetrie; Symmetry; Vibration; classification; diatomic molecule; dynamics; |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-93197-0 |
| isbn_softcover | 978-3-540-11184-9 |
| isbn_ebook | 978-3-642-93197-0Series ISSN 0342-4901 Series E-ISSN 2192-6603 |
| issn_series | 0342-4901 |
| copyright | Springer-Verlag Berlin Heidelberg 1982 |
|Archiver|手机版|小黑屋|
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