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Titlebook: Surface Enhanced Raman Scattering; Richard K. Chang,Thomas E. Furtak Book 1982 Plenum Press, New York 1982 electron.electron energy loss s

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书目名称Surface Enhanced Raman Scattering
编辑Richard K. Chang,Thomas E. Furtak
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图书封面Titlebook: Surface Enhanced Raman Scattering;  Richard K. Chang,Thomas E. Furtak Book 1982 Plenum Press, New York 1982 electron.electron energy loss s
描述In the course of the development of surface science, advances have been identified with the introduction of new diagnostic probes for analytical characterization of the adsorbates and microscopic structure of surfaces and interfaces. Among the most recently de­ veloped techniques, and one around which a storm of controversy has developed, is what has now been earmarked as surface enhanced Raman scattering (SERS). Within this phenomenon, molecules adsorbed onto metal surfaces under certain conditions exhibit an anomalously large interaction cross section for the Raman effect. This makes it possible to observe the detailed vibrational signature of the adsorbate in the ambient phase with an energy resolution much higher than that which is presently available in electron energy loss spectroscopy and when the surface is in contact with a much larger amount of material than that which can be tolerated in infrared absorption experiments. The ability to perform vibrational spectroscopy under these conditions would lead to a new understanding about the chemical identity, geome­ try, and bonding of adsorbed material at a level previously unacces­ sible. It is for these reasons that the last
出版日期Book 1982
关键词electron; electron energy loss spectroscopy; scattering; spectroscopy; surface science
版次1
doihttps://doi.org/10.1007/978-1-4615-9257-0
isbn_softcover978-1-4615-9259-4
isbn_ebook978-1-4615-9257-0
copyrightPlenum Press, New York 1982
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The Image Field Effect: How Important Is It?cement in Raman intensity seen for molecules adsorbed on Ag surfaces. (Reference 2 contains a review.) One of these mechanisms, . now known as the image field effect (IFE) mechanism, considered the interaction between the oscillating di-pole moment induced in the adsorbed molecule and its image in t
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Coupled Excitation Model and Quantum Test of Image Field Effectd molecule and surface plasmons of the metal. Our theory permits a quantum mechanical test to be made of the classical image field effect which is one limiting case of our model. In view of the physical simplicity and ease of calculation of classical theories based on image fields, such a test is im
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The Roles of Surface Roughness W. Wood. observed an “anomalous” optical absorption by thin alkali metal films, which he attributed to their granular structure. Until fairly recently, the focus of the investigations has been almost entirely on the effect of surface roughness on the linear optical response of metals, e.g., the ref
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Enhanced Raman Scattering by Molecules Adsorbed at the Surface of Colloidal Particlesch contribute to enhancement of the Raman signals. Such effects alone can give rise to large enhancements which are sensitive to particle size, shape and optical constants. The theory is formulated in such a way that specific changes in Raman polarizability which occur upon adsorption can be incorpo
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A Model Including Excitation of Surface Plasmon Polaritonsidine are enhanced by a factor 10. 10. or more when adsorbed or deposited on a metal like Ag, as compared to their values in the free state. The problem is to understand the physical processes responsible for such selective and specific enhancements. For several years now, a general theoretical form
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