| 书目名称 | Supported Metal Complexes | | 副标题 | A New Generation of | | 编辑 | F. R. Hartley | | 视频video | | | 丛书名称 | Catalysis by Metal Complexes | | 图书封面 |  | | 描述 | It is now IS years since the first patents in polymer supported metal complex catalysts were taken out. In the early days ion-exchange resins were used to support ionic metal complexes. Soon covalent links were developed, and after an initially slow start there was a period of explosive growth in the mid to late 1970s during which virtually every homogeneous metal complex catalyst ever reported was also studied bound to a support. Both polymers and inorganic oxides were studied as supports, although the great preponderance of workers studied polymeric supports, and of these polystyrene was by far the commonest used. This period served to show that by very careful design polymer-supported metal complex catalysts could have specific advantages over homogeneous metal complex catalysts. However the subject was a complicated one. Merely immobilising a successful metal complex catalyst to a functionalised support rarely yielded other than an inferior version of the catalyst. Amongst the many discouraging results of the 1970s, there were more than enough results that were sufficiently encouraging to demonstrate that, by careful design, supported metal complex catalysts could be prepared i | | 出版日期 | Book 1985 | | 关键词 | ITIES; Ion; Ruthenium; Zirconium; bonding; catalysis; catalyst; cobalt; iridium; metals; nickel; platinum; polym | | 版次 | 1 | | doi | https://doi.org/10.1007/978-94-009-5247-8 | | isbn_softcover | 978-94-010-8817-6 | | isbn_ebook | 978-94-009-5247-8Series ISSN 0920-4652 Series E-ISSN 2215-180X | | issn_series | 0920-4652 | | copyright | D. Reidel Publishing Company 1985 |
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发表于 2025-3-21 18:29:52
