Titlebook: Sulfur-Mediated Rearrangements I; Ernst Schaumann Book 2007 Springer-Verlag Berlin Heidelberg 2007 Organic Chemistry.Rearrangement.Rearran

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precede

https://doi.org/10.1007/978-3-540-68098-7Organic Chemistry; Rearrangement; Rearrangement Reactions; Rearrangement reaction; Sulfur Compounds

languor

978-3-642-08777-6Springer-Verlag Berlin Heidelberg 2007

AVOW

Sulfur-Mediated Rearrangements I978-3-540-68098-7Series ISSN 0340-1022 Series E-ISSN 1436-5049

Adrenaline

兽群

Sulfur is More Than the Fat Brother of Oxygen. An Overview of Organosulfur Chemistry,A survey of the structure and synthetic applications of organosulfur compounds is given. Theemphasis is on the key features of organosulfur chemistry.

CHARM

Synapse

性学院

1,2-Sulfur Migrations,ontrol;substitution or elimination to open the thiiranium ring also proceeds stereoselectively. This and othertypes of 1,2-thio migration, including 1,2-thio shifts, formal 1,2-thio migration through fragmentation-recombination,[1,5]∼thio migration in five-membered ring systems, and radical 1,2-thio migrations are discussedin this review.

绊住

1,3-Sulfur Shifts: Mechanism and Synthetic Utility,Allylic sulfurshifts have been used in the synthesis of sulfides and sulfones of higher complexity, the stereospecificsynthesis of alkenes, and the construction of ketones. This comprehensive survey of 1,3-sulfur migrationspays particular attention to the reported mechanisms and synthetic application.