| 书目名称 | Studies on Green Synthetic Reactions Based on Formic Acid from Biomass | | 编辑 | Ming-Chen Fu | | 视频video | | | 概述 | Nominated as an outstanding Ph.D. thesis by the University of Science and Technology of China.Develops a new method for preparing ß, ?-unsaturated carboxylic acids.Demonstrates that the combination of | | 丛书名称 | Springer Theses | | 图书封面 |  | | 描述 | This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. | | 出版日期 | Book 2020 | | 关键词 | Formic Acid; Methylation; Unsaturated Carboxylic Acids; Carbonylation; Hydrocarboxylation; Carbon monoxid | | 版次 | 1 | | doi | https://doi.org/10.1007/978-981-15-7623-2 | | isbn_softcover | 978-981-15-7625-6 | | isbn_ebook | 978-981-15-7623-2Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |
The information of publication is updating
|
|
发表于 2025-3-21 19:32:54
