书目名称 | State-to-State Dynamical Research in the F+H2 Reaction System |
编辑 | Zefeng Ren |
视频video | |
概述 | Nominated as an outstanding contribution by Dalian Institute of Chemical Physics, Chinese Academy of Sciences.Introduces a new crossed molecular beam scattering apparatus with a high time-of-flight re |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | .This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.. |
出版日期 | Book 2014 |
关键词 | Born-Oppenheimer Approximation; Crossed Molecular Beam Scattering; Differential Cross Section; Feschbac |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-642-39756-1 |
isbn_softcover | 978-3-642-39755-4 |
isbn_ebook | 978-3-642-39756-1Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer-Verlag Berlin Heidelberg 2014 |