Titlebook: Solvomercuration / Demercuration Reactions in Organic Synthesis; Richard C. Larock Book 1986 Springer-Verlag Berlin Heidelberg 1986 Alkene

愚蠢人

暂时过来

Overview: 978-3-642-88206-7978-3-642-88204-3

种类

Hydroxymercuration,. Although this reaction is commonly referred to as oxymercuration, we shall henceforth call it hydroxymercuration to help distinguish it from other reactions which also introduce oxygen functionality on to an alkene. This reaction has been briefly reviewed several times [1-6].

Offbeat

Peroxymercuration,9 by Sokolov and Reutov in Russia [1] and Bloodworth and co-workers in England [2] provides a useful approach to peroxides. The work in this area is summarized in Table 4.1, which is divided into simple alkenes, alkenyl hydroperoxides and finally dienes. Our discussion will be similarly organized.

Bravura

Acyloxymercuration,es by heating alkenes with mercuric carboxylate salts. The most common reaction to occur between an alkene and a mercuric carboxylate salt is not, however, either of these processes, but simple addition of the mercury and carboxylate groups across the carbon—carbon double bond, acyloxymercuration (Eq. 1).

mercenary

Introduction,rcury moiety and solvent or nucleophile have added across the carbon — carbon unsaturation. This reaction, most commonly called solvomercuration today, has been known since the turn of the century. With the relatively recent development of convenient methods for replacing the mercury moiety by hydro

周年纪念日

Hydroxymercuration,. Although this reaction is commonly referred to as oxymercuration, we shall henceforth call it hydroxymercuration to help distinguish it from other reactions which also introduce oxygen functionality on to an alkene. This reaction has been briefly reviewed several times [1-6].

假

DAMN

不透明

ed platelet activation (TCIPA), which provide an insight into the molecular mechanisms of TCIPA and allow searching for potential inhibitors. In this chapter, we describe the two most prominent experimental assays to follow TCIPA, namely platelet aggregation and platelet granule secretion, experimen