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Titlebook: Solvation Dynamics; A Notion of Charge I Chang Q Sun Book 2019 Springer Nature Singapore Pte Ltd. 2019 molecular nonbond interaction.solvat

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书目名称Solvation Dynamics
副标题A Notion of Charge I
编辑Chang Q Sun
视频video
概述Highlights the latest advances and outlines future trends in aqueous solvation dynamics.Reinforces the principles of charge injection for modulating the hydrogen-bond network and solution properties.P
丛书名称Springer Series in Chemical Physics
图书封面Titlebook: Solvation Dynamics; A Notion of Charge I Chang Q Sun Book 2019 Springer Nature Singapore Pte Ltd. 2019 molecular nonbond interaction.solvat
描述This book highlights the latest advances and outlines future trends in aqueous solvation studies from the perspective of hydrogen bond transition by charge injection, which reconciles the solvation dynamics, molecular nonbond interactions, and the extraordinary functionalities of various solutes on the solution bond network and properties. Focus  is given on ionic and dipolar electrostatic polarization, O:H nonbond interaction, anti-HB and super-HB repulsion, and solute-solute interactions. Its target audience includes researchers, scientists, and engineers in chemistry, physics, surface and interface science, materials science and engineering.   
出版日期Book 2019
关键词molecular nonbond interaction; solvation dynamics; solution bond network; dipolar electrostatic polariz
版次1
doihttps://doi.org/10.1007/978-981-13-8441-7
isbn_softcover978-981-13-8443-1
isbn_ebook978-981-13-8441-7Series ISSN 0172-6218 Series E-ISSN 2364-9003
issn_series 0172-6218
copyrightSpringer Nature Singapore Pte Ltd. 2019
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Theory: Aqueous Charge Injection by Solvation,g- and short-range interaction. A solute interacts with its neighboring H.O molecules through the O:H vdW, O:⇔:O super-HB compression, H↔H anti-HB fragilization, ionic or dipolar polarization with screen shielding, and solute-solute interaction and their combinations. The hydration H.O dipoles tend
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,Lewis Acidic Solutions: H↔H Fragilization, 3% shorter and the associated O:H nonbond is 60% longer than normal. The H↔H compression shortens its nearest O:H nonbond by 11% and lengthens the H–O by 4%. The X. point polarizer shortens the H–O bond and stiffens its phonon but relax the O:H nonbond oppositely in the supersolid hydration shell.
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Organic Molecules: Dipolar Solutes,nt from that of ordinary water. The naked lone pairs and protons are equally capable of interacting with the solvent H.O molecules to form O:H vdW bond, O:⇔:O super–HB or H↔H anti-HB without charge sharing or new bond forming. Solvation examination of alcohols, aldehydes, formic acids, and sugars re
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Multifield Coupling,he same sequence of phase transition for pure water. P. and P. vary simultaneously with the solute type in the Hofmeister series order: I > Br > Cl > F ~ 0. However, the P. grows faster than the P. with the increase of NaI/H.O concentration, following the (P, T) path upwardly along the Liquid-VI pha
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