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Titlebook: Solid Electrolytes and Their Applications; E. C. Subbarao Book 1980 Plenum Press, New York 1980 X-ray.calcium.crystal.foundation.liquid.ma

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Defect Structure and Transport Properties,resence of ionic defects gives rise to ionic conductivity, while that of electronic defects results in electronic conductivity, which is undesirable in a solid electrolyte. In practice, for a solid electrolyte to be useful, the ratio of ionic to electronic conductivity should be 100 or greater.
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Kinetic Studies,nvolve the measurement of either the current or the voltage across an electrochemical cell as a function of time. Since currents and voltages can be measured more precisely than volume, weight, composition, etc., the accuracy involved in electrochemical kinetic measurements is much higher. However, the technique is limited to specific systems.
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Fabrication, ceramic, or glass components. In all applications, the electrolyte has to be contacted with an appropriate metallic or nonmetallic electrode in solid or liquid state. These aspects are discussed in the present chapter.
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Limiting Factors in Measurements Using Solid Electrolytes,ynamic measurements received much of its impetus from the work of Kiukkola and Wagner. and Peters ... They introduced the use of ZrO.-base and ThO.-base solid electrolytes for the determination of the standard free energy of formation of oxides. As early as 1943, Wagner had explained transport mecha
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Thermodynamic Studies of Alloys and Intermetallic Compounds,ponent . in the alloy phase α as a function of composition and temperature is in principle a sufficient property to characterize the alloy system. Hence the development of experimental methods specific to alloy thermodynamics has been in obtaining more reliable chemical potential data over wider tem
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