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Titlebook: Soft Crystals; Flexible Response Sy Masako Kato,Kazuyuki Ishii Book‘‘‘‘‘‘‘‘ 2023 The Editor(s) (if applicable) and The Author(s) 2023 stimu

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Theoretical Background of Photophysical Propertiestal photophysical properties of molecular monomers, such as electronic absorption spectra and luminescence properties, are introduced. Moreover, the photophysical properties of molecular dimers and molecular crystals are explained in terms of intermolecular interactions in excited states.
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Vapochromic Soft Crystals Constructed with Metal Complexesing sensor materials to detect harmful substances in the environment. In addition, vapochromism is scientifically interesting for the direct visualization of interactions between gases and solids. The crystals of metal complexes involve diverse and flexible electronic interactions, such as metal–met
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Luminescent Mechanochromism and the Photosalient Effect of Aryl Gold(I) Isocyanide Complexess attracted much attention owing to potential application in sensors and actuators. Our group has intensively studied aryl gold(I) isocyanide complexes to develop stimuli-responsive molecular crystals that can show luminescent mechanochromism and crystal jumping through phase transitions induced by
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Elastic and Plastic Soft Crystals with Superelasticity, Ferroelasticity, and Superplasticityvery in Au–Cd alloys in 1932, superelasticity had been believed to be limited to certain alloys until the discovery of “organic superelasticity” in 2014, which revealed it to be a general phenomenon observed in organic crystals along with ferroelasticity—reversible plastic deformability that is not
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Thermosalient Phenomena in Molecular Crystals: A Case Study of Representative Moleculesre, we review the crystal jumping phenomena under a thermal stimulus (thermosalient phenomenon). Thermosalient phenomena are characterized by thermal phase transitions and anisotropic lattice expansion/contraction at a microscopic scale and jumping behavior through bending/deformation/rotation/cleav
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Molecular Crystal Calculation Prospects for Structural Phase Transitionsd develop new methodologies. The accuracy of first-principles calculations for molecular crystals has rapidly improved over the last decade with the contribution of the Cambridge Crystallographic Data Centre blind test, which predicts the crystal structure from the structural formula. However, it is
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