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Titlebook: Size Exclusion Chromatography; B. J. Hunt,S. R. Holding Book 1989 Springer Science+Business Media Dordrecht 1989 chromatography.developmen

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书目名称Size Exclusion Chromatography
编辑B. J. Hunt,S. R. Holding
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图书封面Titlebook: Size Exclusion Chromatography;  B. J. Hunt,S. R. Holding Book 1989 Springer Science+Business Media Dordrecht 1989 chromatography.developmen
描述There is a large and increasing variety of polymers currently in use both for domestic and industrial applications. The properties of polymers are deter­ mined not only by their chemical type, but also by their molecular mass and molecular mass distributions. However, while the chemical type of polymers can be determined relatively easily, the average molecular masses and molecular mass distributions are more difficult to measure. The molecular mass averages of a polymer are measured by specialized and complex techniques such as light scattering (for weight average) and osmometry (for number average). Thus, complete characterization of the molecular mass distribution of a polymer by such means requires separating the sample into many fractions which can then be examined individually. Since size exclusion chromatography was introduced as a rapid and straightforward technique for the characterization of polymer molecular mass distributions, there have been tremendous increases in development and applications, and it was felt appropriate to bring together into a single volume the information required by scientists from many disciplines who wish to use the technique. This book should b
出版日期Book 1989
关键词chromatography; development; distribution; information; polymer; scattering
版次1
doihttps://doi.org/10.1007/978-1-4615-7861-1
isbn_softcover978-1-4615-7863-5
isbn_ebook978-1-4615-7861-1
copyrightSpringer Science+Business Media Dordrecht 1989
The information of publication is updating

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Theoretical backgroundcussed. It is hoped that this information will enable the newcomer to size exclusion chromatography to interpret chromatograms and the resultant numeric data correctly and with the care necessary to recognize spurious results and anomalous behaviour which he is certain to observe on occasions.
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Theoretical backgroundhy in general and size exclusion chromatography (SEC) in particular. The reader who requires a detailed theoretical treatise is referred to the many excellent texts which have previously been published [1–8]. However, as this book is aimed at the practising chromatographer, it is appropriate to prov
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Calibration and data analysiserimental practice is now often relatively straightforward. Also, the complex data manipulation is now normally carried out using a dedicated data-handling system which produces the calculated molecular mass averages and distributions at the touch of a few keys. Unfortunately, this apparent ease of
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High-temperature size exclusion chromatographytic polymers was appreciated early [1]. It was developed, however, for low-temperature application principally for reasons of safety and ease of use. Tetrahydrofuran, THF, had been adopted as a general-purpose mobile phase, and its low boiling point and the ease with which it formed peroxides restri
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Copolymer analysisition and molecular mass distributions. Therefore, we must know average values of molecular mass and composition, and their distributions. These two distributions are inherently independent of each other. However, it is not easy to determine the molecular mass distribution (MMD) independently of the
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