Titlebook: Selectivity in the Synthesis of Cyclic Sulfonamides; Application in the S Kimberly Geoghegan Book 2014 Springer International Publishing Sw

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Book 2014eaction sequence. This regioselective Heck reaction, combined with the reductive removal of the temporary amino-protecting group, allowed us to synthesize the Sceletium alkaloids: mesembrane, mesembranol and mesembrine.

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An Investigation into the One-Pot Heck Olefination-Hydrogenation Reaction, molecules. Taking inspiration from nature, where multi-enzymatic systems carry out two or more transformations to access structurally intricate molecules, one-pot procedures involving multiple catalytic events, i.e. multi-task, or cascade/tandem/domino processes, are being sought by synthetic chemists.

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Double Reduction of Cyclic Aromatic Sulfonamides,tantly, the basicity/nucleophilicity of the nitrogen atom is reduced dramatically due to the presence of the electron-withdrawing sulfonyl moiety. Unlike their carbamate or amide analogues, there are no spectroscopic problems associated with rotamers when employing sulfonamides as protecting group.