| 书目名称 | S Sulfur-Nitrogen Compounds | | 副标题 | Compounds with Sulfu | | 编辑 | Hans-Jürgen Fachmann,Reimund Jotter,Joachim Wagner | | 视频video | | | 丛书名称 | Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition | | 图书封面 |  | | 描述 | The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studie | | 出版日期 | Book 1989Latest edition | | 关键词 | Oxidation; chemistry; metals | | 版次 | 8 | | doi | https://doi.org/10.1007/978-3-662-06357-6 | | isbn_ebook | 978-3-662-06357-6 | | copyright | Springer-Verlag Berlin Heidelberg 1989 |
The information of publication is updating
|
|
发表于 2025-3-21 18:23:28
