| 书目名称 | Reactivity of Nitric Oxide on Copper Surfaces |
| 副标题 | Elucidated by Direct |
| 编辑 | Akitoshi Shiotari |
| 视频video | |
| 概述 | Nominated by Kyoto University as an outstanding Ph.D. thesis.Provides in the introduction a comprehensive overview of previous studies on NO/metal systems.Helps the reader to understand the experiment |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed onto the surfaces have been significant challenges faced by conventional experimental techniques, such as vibrational spectroscopies. The author investigated "individual" NO molecules on Cu surfaces using low-temperature scanning tunneling microscopy (STM). STM not only provides information on the geometric, electronic, and vibrational properties at the single-molecule level; it is also able to manipulate molecules on surfaces to induce chemical reaction. Exploiting those techniques, the author chemically identified individual NO-related species on the surfaces and discovered new reaction processes for NO reduction, which provides microscopic insights into the catalytic mechanisms. The authoralso visualized wave functions of electrons in a valence orbital of NO and demonstrated that the wave functions are modified by the formation of covalent bonding or hydrogen bonding. This is, namely, |
| 出版日期 | Book 2017 |
| 关键词 | surface reaction of nitric oxide; visualization of molecular orbitals; chemical reaction on copper sur |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-981-10-4582-0 |
| isbn_softcover | 978-981-13-5174-7 |
| isbn_ebook | 978-981-10-4582-0Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | Springer Nature Singapore Pte Ltd. 2017 |
发表于 2025-3-21 18:43:49
