Titlebook: Reaction Mechanisms in Carbon Dioxide Conversion; Michele Aresta,Angela Dibenedetto,Eugenio Quaranta Book 2016 Springer-Verlag Berlin Heid

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,Interaction of CO2 with C–C Multiple Bonds,d cumulated dienes, to give carboxylated products. This chapter focuses on the main mechanistic features of these carboxylation processes. A key step of these transformations is the metal-promoted oxidative coupling reaction between CO. and the unsaturated substrate. The mechanistic details of this

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Reaction Mechanisms in the Direct Carboxylation of Alcohols, Polyols, Cyclic Ethers, and Cyclic Ami linear carbonates, cyclic monomeric carbonates, and polycarbonates. Homogeneous, heterogenized, and heterogeneous catalysts are described. The problem of “water elimination” is considered and routes for water-trapping discussed. DFT calculations used to support the reaction mechanism are presented

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Thermodynamics and Applications of CO2 Hydrates,stable under high pressure and low temperature. CO. hydrates, specifically, are composed of CO. as the guest molecule and water as the host molecule. CO. hydrates have a number of applications including CO. capture, cold storage, CO. sequestration, and, lately, the direct displacement of methane hyd

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,Insertion of CO2 into E–X Bonds,nds in which CO. may be implied (C–C bonds or C–E bonds) and thus to the conversion of CO. into added-value chemicals. The insertion product can be thermodynamically and kinetically stable or labile, offering in the latter case the opportunity of a catalytic path.

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Reaction Mechanisms in the Direct Carboxylation of Alcohols, Polyols, Cyclic Ethers, and Cyclic Amim of “water elimination” is considered and routes for water-trapping discussed. DFT calculations used to support the reaction mechanism are presented with the identified transition states relevant to various mechanistic scenarios.

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archers, teachers and PhD students.Analyses reaction mechaniThis book provides an analysis of the reaction mechanisms relevant to a number of processes in which CO2 is converted into valuable products. Several different processes are considered that convert CO2 either in specialty chemicals or in bu