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Titlebook: Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batt; Snehashis Choudhury Book 2019 Spring

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书目名称Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batt
编辑Snehashis Choudhury
视频video
概述Nominated as an outstanding PhD thesis by Cornell University.Provides an introduction to lithium battery science and related design principles.Proposes new criteria to stabilize dendrite growth along
丛书名称Springer Theses
图书封面Titlebook: Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batt;  Snehashis Choudhury Book 2019 Spring
描述.This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. Thi
出版日期Book 2019
关键词lithium-ion battery; nanoparticle-polymer hybrid electrolyte; dendrite growth; multiscale modeling of i
版次1
doihttps://doi.org/10.1007/978-3-030-28943-0
isbn_softcover978-3-030-28945-4
isbn_ebook978-3-030-28943-0Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightSpringer Nature Switzerland AG 2019
The information of publication is updating

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A Highly Reversible Room-Temperature Lithium Metal Battery Based on Cross-Linked Hairy Nanoparticleanced energy storage technologies based on metallic Li, Na, and Al electrodes. Solid polymer electrolytes and nanoparticle-polymer composites have shown promise as candidates to suppress Li dendrite growth, but the challenge of simultaneously maintaining high mechanical strength and high ionic condu
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Electroless Formation of Hybrid Lithium Anodes for High Interfacial Ion Transport,inetics of liquids at solid interfaces. It is known that the intrinsic chemical instability of the metals to undergo parasitic side reactions with liquid electrolytes presents a difficult challenge for long-term stability. Approaches that allow facile creation of uniform coatings on these metals to
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Designer Interphases for the Lithium-Oxygen Electrochemical Cell,m for portable electrical energy storage. Such lithium-oxygen (Li-O.) cells offer theoretical specific energies competitive with fossil fuels and have long been considered an important storage technology for enabling electrified transportation. Multiple, fundamental challenges with the cathode, anod
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