书目名称 | Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batt |
编辑 | Snehashis Choudhury |
视频video | |
概述 | Nominated as an outstanding PhD thesis by Cornell University.Provides an introduction to lithium battery science and related design principles.Proposes new criteria to stabilize dendrite growth along |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | .This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. Thi |
出版日期 | Book 2019 |
关键词 | lithium-ion battery; nanoparticle-polymer hybrid electrolyte; dendrite growth; multiscale modeling of i |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-030-28943-0 |
isbn_softcover | 978-3-030-28945-4 |
isbn_ebook | 978-3-030-28943-0Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer Nature Switzerland AG 2019 |