| 书目名称 | Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory | | 编辑 | Elise Kochanski (Director) | | 视频video | | | 丛书名称 | Nato Science Series C: | | 图书封面 |  | | 描述 | The scope of this paper is to recall fundamental notions of the molecular spectroscopy and dynamics, necessary for discussion of photophysical and photochemical processes in condensed phases. We will thus treat in a more detailed way the specific features which are important for molecular systems strongly interacting with their environment. Other aspects such as the time evolution of isolated molecules, single-level excitation and state-to-state chemistry, important for the gas-phase photophysics are omitted. We start (Sec.2) with a brief description of radiative processes (light absorption and emission) in molecules. In the quantum-mechanical treatment of this problem, the appropriate basis is that of so-called zero-order states, corresponding to the traditional scheme of electronic states (singlets, doublets, triplets etc.) and vibrational levels belonging to each state. The important point will be deduction of selection rules for most radiative transitions. At this stage all molecular states are considered as stationary states. In order to treat the breakdown of simple selection rules and non-radiative transitions between individual molecular states, it is necessary to take into | | 出版日期 | Book 1992 | | 关键词 | chemistry; metals; photochemistry; protein; transition metal | | 版次 | 1 | | doi | https://doi.org/10.1007/978-94-011-2698-4 | | isbn_softcover | 978-94-010-5195-8 | | isbn_ebook | 978-94-011-2698-4Series ISSN 1389-2185 | | issn_series | 1389-2185 | | copyright | Springer Science+Business Media Dordrecht 1992 |
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