| 书目名称 | Organotrifluoroborate Preparation, Coupling and Hydrolysis | | 编辑 | Alastair J. J. Lennox | | 视频video | | | 概述 | Nominated as an outstanding Ph.D. thesis by the University of Bristol, UK.Includes an extensive review on organotrifluoroborate salts.Demonstrates a new, simple and etch-free preparation method for or | | 丛书名称 | Springer Theses | | 图书封面 |  | | 描述 | Alistair Lennox‘s thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis. | | 出版日期 | Book 2013 | | 关键词 | Cross-coupling; Glassware Etching; Kinetics of Hydrolysis; Organotrifluoroborate Salts; Side-product Sup | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-319-01134-9 | | isbn_softcover | 978-3-319-37734-6 | | isbn_ebook | 978-3-319-01134-9Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | Springer International Publishing Switzerland 2013 |
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书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis影响因子(影响力)
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis影响因子(影响力)学科排名
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis网络公开度
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis网络公开度学科排名
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis被引频次
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis被引频次学科排名
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis年度引用
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书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis读者反馈
书目名称Organotrifluoroborate Preparation, Coupling and Hydrolysis读者反馈学科排名
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发表于 2025-3-21 16:11:02
