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Titlebook: Organosilicon Derivatives of Phosphorus and Sulfur; S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits Book 1971 Springer Science+Business Media

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书目名称Organosilicon Derivatives of Phosphorus and Sulfur
编辑S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits
视频video
丛书名称Monographs in Inorganic Chemistry
图书封面Titlebook: Organosilicon Derivatives of Phosphorus and Sulfur;  S. N. Borisov,M. G. Voronkov,E. Ya. Lukevits Book 1971 Springer Science+Business Media
描述One of the characteristics of the development of chemical science in the middle of the present century is the vigorous pro­ gress of the "third chemistry," which is often named now the chemistry of heteroorganic compounds. Then in the last decade, among specialists in this field there has been a marked increase in interest in heteroatomic organic derivatives of silicon, i. e. , heteroorganic silicon compounds. However, until recently this new class of chemical substances, which is extremely interesting theoretically and practically, has been without a single specialized monograph which systematizes and generalizes all progress in the heteroorganic chemistry of silicon. The first attempt in this direction was our book "Heteroorganic Compounds of Silicon" [42 (F), 17 (S) *], which appeared at the end of 1966 and was published as an English translation in the USA in 1969. However, as follows from its subtitle "Derivatives of Inorganic Elements," this mono­ graph could not cover the whole broad field of the chemistry of heteroorganic compounds of silicon. The main reason for this was above all the abundance and variety of original investigations of organosilicon derivatives of inorgani
出版日期Book 1971
关键词Silane; chemistry; development; organic chemistry; oxygen; phosphorus; silicon; sodium; translation
版次1
doihttps://doi.org/10.1007/978-1-4684-0727-3
isbn_softcover978-1-4684-0729-7
isbn_ebook978-1-4684-0727-3
copyrightSpringer Science+Business Media New York 1971
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Organosilicon Derivatives of Phosphorus and Sulfur
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Organosilicon Derivatives of Phosphorus and Sulfur978-1-4684-0727-3
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as follows from its subtitle "Derivatives of Inorganic Elements," this mono­ graph could not cover the whole broad field of the chemistry of heteroorganic compounds of silicon. The main reason for this was above all the abundance and variety of original investigations of organosilicon derivatives of inorgani978-1-4684-0729-7978-1-4684-0727-3
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Organosilicon Derivatives of Phosphorus,When a mixture of trimethylchlorosilanes and anhydrous orthophosphoric acid (molar ratio 3: 1) is heated to boiling [62a] or when H.PO. is added gradually to trimethylchlorosilane [430, 525, 526], hydrogen chloride is liberated and tris(trimethylsilyl) phosphate is formed:
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Organosilicon Derivatives of Sulfur,The first compound of silicon containing the grouping Si—S—H was obtained in 1847 by passing a mixture of hydrogen sulfide and silicon tetrachloride through a red-hot porcelain tube. However, the substance formed was then taken to be C1.SiS [554–561].
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