书目名称 | Organometallics for Green Catalysis |
编辑 | Pierre H. Dixneuf,Jean-François Soulé |
视频video | |
概述 | Provides an overview of the latest innovative organometallic catalysts including pincer and cyclometalated complex structures.Discusses transformation of raw-materials into fine chemicals involving CO |
丛书名称 | Topics in Organometallic Chemistry |
图书封面 |  |
描述 | .This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol –an eco-friendly energy storage strategy– and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C–O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C–H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C–H bond oxidation using visible light leads mainly to the formation of C– |
出版日期 | Book 2019 |
关键词 | Metal-Catalyzed Hydrogenation; N-Methyl amines; N-Formyl amines; Methanol; Carbonyl Compounds |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-030-10955-4 |
isbn_ebook | 978-3-030-10955-4Series ISSN 1436-6002 Series E-ISSN 1616-8534 |
issn_series | 1436-6002 |
copyright | Springer Nature Switzerland AG 2019 |