| 书目名称 | Organometallic Compounds | | 副标题 | Volume Two: The Tran | | 编辑 | G. E. Coates,M. L. H. Green,K. Wade | | 视频video | | | 图书封面 |  | | 描述 | to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bon | | 出版日期 | Book 1968 | | 关键词 | chromium; copper; gold; manganese; metals; molybdenum; nickel; olefine; organometallic chemistry; palladium; p | | 版次 | 1 | | doi | https://doi.org/10.1007/978-94-011-6893-9 | | isbn_softcover | 978-94-011-6895-3 | | isbn_ebook | 978-94-011-6893-9 | | copyright | M. L. H. Green 1968 |
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