Titlebook: Organometallic Chemistry of the Transition Elements; Florian P. Pruchnik,Stan A. Duraj Book 1990 Springer Science+Business Media New York

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https://doi.org/10.1007/978-1-4899-2076-8Organometallic chemistry; metals; transition element

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,Complexes Containing Three-Electron Π-Ligands,The allyl group C.R. (R = H, alkyl, or aryl) may behave as an .. ligand which forms a . bond with the metal (a) or it may behave as an .. (Π) ligand. The .. allyl group may be bonded to the metal in a symmetrical fashion (b), with equivalent terminal carbon atoms, or it may be bonded in an asymmetrical way (c).(.)

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,Compounds Containing Four-Electron π-Ligands,The following compounds are classified as 4. ligands: 1,3-dienes, cyclobutadiene, and trimethylenemethane, and their derivatives.

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,Compounds Containing Five-Electron π-Ligands,The most typical 5. dienyl ligands are five-, six-, and seven-membered cyclic and some acyclic hydrocarbons. . The simplest ligand of this type is cyclopentadienyl in which all carbon atoms are equivalent and lie in the same plane.

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Application of Organometallic Compounds in Homogeneous Catalysis,Catalysis belongs to older domains of chemistry. The term catalysis was introduced by Berzelius in 1835, and some catalytic processes date back to the beginning of the 19th century, for example, combustion of hydrogen in the presence of platinum or breakdown of many organic compounds by acids.

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978-1-4899-2078-2Springer Science+Business Media New York 1990

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