Titlebook: Organometallic Chemistry and Catalysis; Karl Kirchner,Walter Weissensteiner Book 2001 Springer-Verlag Wien 2001 Inorganic Chemistry.Organo

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Syntheses and Crystal Structures of Polynuclear Cu(I) Complexes Containing the 1,1′-Bis-(diphenylphorystal packing with large open channels containing water. Finally, DFT calculations on a model of . showed that its HOMO exhibits, besides Fc, a significant Cu and Cl character, which is reflected in its electrochemical properties.

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Recent Chemistry Based on the [Ru,(CH,CN),], Cation: Reappraisal of an Old Precursorsubstitution reactions are a dominant feature of this complex. Important derivatives are the highly reactive complexes [Ru.(P..(CH.CN).]. which are a source of the 14e. fragment [Ru.(P..)].. These species are catalytically active in the redox isomerization of allyl alcohols to give aldehydes and ket

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Palladium Chemistry Related to Benzyl Bromide Carbonylation: Mechanistic Studieshloroform or benzene to Pd(0) complexes Pd(PR.). and Pd(P..).(NEt.).. The same reaction performed in the presence of air gave CH.CHO or CH.CH.CHO when N.. was used instead of NEt.. Pd(P(OPh).). reacted with benzyl bromide affording the oxidative addition product .-PdBr(CH.Ph)(P(OPh).).. The reaction

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A Novel Infinite 1-D Chain of Silver(I) Bridged by ,-Azobenzenerized by X-ray single crystal diffraction. The crystal consists of 1-D zigzag cationic chains made up from [Ag(H.0)]. units linked by .-azobenzene bridges and BF4−anions. Hydrogen bonding interactions between the chains and BF