书目名称 | Organometallic Bonding and Reactivity |
副标题 | Fundamental Studies |
编辑 | John M. Brown,Peter Hofmann |
视频video | |
丛书名称 | Topics in Organometallic Chemistry |
图书封面 |  |
描述 | The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experim |
出版日期 | Book 1999 |
关键词 | Metallorganische Chemie; Metallorganische Katalyse; Organische Synthese; Organometallchemie; Organometal |
版次 | 1 |
doi | https://doi.org/10.1007/3-540-69707-1 |
isbn_softcover | 978-3-662-14223-3 |
isbn_ebook | 978-3-540-69707-7Series ISSN 1436-6002 Series E-ISSN 1616-8534 |
issn_series | 1436-6002 |
copyright | Springer-Verlag Berlin Heidelberg 1999 |