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Titlebook: Organic Synthesis via Organometallics (OSM 4); Proceedings of the F Dieter Enders,Hans-Joachim Gais,Wilhelm Keim Conference proceedings 199

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书目名称Organic Synthesis via Organometallics (OSM 4)
副标题Proceedings of the F
编辑Dieter Enders,Hans-Joachim Gais,Wilhelm Keim
视频video
图书封面Titlebook: Organic Synthesis via Organometallics (OSM 4); Proceedings of the F Dieter Enders,Hans-Joachim Gais,Wilhelm Keim Conference proceedings 199
出版日期Conference proceedings 1993
关键词Chemie; Kohlenstoff; Organometallchemie; Oxidation; Reaktionen; Rearrangement; Synthese; Wasserstoff; metall
版次1
doihttps://doi.org/10.1007/978-3-322-84062-2
isbn_softcover978-3-528-06481-5
isbn_ebook978-3-322-84062-2
copyrightFriedr. Vieweg & Sohn Verlagsgesellschaft mbH, Braunschweig/Wiesbaden 1993
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Application of High Pressure Techniques in Mechanistic and Synthetic Studies of Organometallic Systofiles is discussed. The characteristic pressure dependence of these reactions create the possibility to selectively tune the reactivity of, and product distribution for such organometallic systems. The effects are in many cases so significant that moderate pressures (up to 100 MPa) are sufficient to induce certain synthetic processes.
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,Configurationally Stable and Configurationally Labile Chiral α-Substituted Organolithium Compounds 3:7 may be realized upon quenching with electrophiles. The configurational stabi- * lity of these and related α-heterosubstituted organolithium have been rapidly assessed by a test based on kinetic resolution.
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