Titlebook: Organic Reaction Mechanisms; 40 Solved Cases Mar Gómez Gallego,Miguel A. Sierra Textbook 2004 Springer-Verlag Berlin Heidelberg 2004 Anorga

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Level 1 — Case 10 Nucleophile Versus Base Catalysisechanisms for amine-catalyzed reactions of carbonyl compounds involve acylium ion and ketene intermediates (the latter can only occur for acid halides containing α-hydrogens), but the actual role of the catalyst is still uncertain.

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nd thermodynamic data, isotopic labelling and organic reactivity. The book makes an excellent primer for advanced undergraduates in chemistry who are preparing for exams and is also useful for graduate students and instructors..978-3-642-62292-2978-3-642-18788-9

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Level 2 — Case 19 Chelate-Controlled Carbonyl Addition Reactions SnCl. was employed, aldols . were obtained preferentially with selectivities higher than 95:5. Instead, the stereoisomers . were isolated with nearly total stereoselectivity when Me.AlCl (2 eq) was used to promote the reaction (Scheme 19.1a and b)..