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Titlebook: Optically Active Polymers; Eric Selegny Book 1979 D. Reidel Publishing Company, Dordrecht, Holland 1979 biopolymer.macromolecule.polymer.p

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书目名称Optically Active Polymers
编辑Eric Selegny
视频video
丛书名称Charged and Reactive Polymers
图书封面Titlebook: Optically Active Polymers;  Eric Selegny Book 1979 D. Reidel Publishing Company, Dordrecht, Holland 1979 biopolymer.macromolecule.polymer.p
描述The first four volumes of the series on ‘Charged and Reactive Polymers‘ have been devoted to polymers in solution (Voh. I and II) or in gel and membrane forms (Vols. III and IV). In correlation with charges, other physical or chemical properties of macro­ molecules have been considered. Understanding of charge and hydrophobic effects is equally important for synthetic and biopolymers or their systems. Optically Active Polymers are related to problems of the same class, since optical activity is an inherent property of both natural macromolecules as well as a great variety of polymers synthesized in the Jast twenty years. Optical activity is a physical spectral property of chiral matter caused by asymmetrical configurations, conformations and structures which have no plane and no center of symmetry and consequently have two mirror image enantiomeric forms of inverse optical rotation. The racemic mixture of chiral enantiomers is optically inactive. The most common form of optical activity was first measured at a constant wavelength by the angle of rotation of linearly polarized light. More recently the measurements have been extended to the entire range of visible and attainable ultr
出版日期Book 1979
关键词biopolymer; macromolecule; polymer; polymerization; synthesis
版次1
doihttps://doi.org/10.1007/978-94-009-9378-5
isbn_softcover978-94-009-9380-8
isbn_ebook978-94-009-9378-5
copyrightD. Reidel Publishing Company, Dordrecht, Holland 1979
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Synthesis of Optically Active Polymers from Unsaturated Monomers,lly active catalysts. separation in fractions having optical rotation with opposite sign of polymer from racemic monomers has also been performed..In the case . asymmetric induction polymerization has been successfully used in addition to the above methods..Stereoregulated copolymerization of optica
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Modification of Chiral Properties Due to Interaction of Polymers and Small Molecules or Ions,s, complexes and inclusion compounds from optically active polymers. Cationic dyes (e.g. acridine orange, methylene blue) are attached to optically active polyelectrolytes in a quite regular manner resulting in strong induced Cotton effects around the absorption maximum of the inactive dyes. An amyl
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,Optical Activity of Reactive ‘Non Regular’ Synthetic Polymers. Properties and Applications, function of the degree of reaction is observed. In the last section, an attempt is made to explain this feature from simple assumptions based on neighboring effects of the different monomeric units present in a partially modified polymer.
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Synthesis, Ring Opening Study and Properties of Some New Polyampholytes from Substituted Aziridinesproperties as metal complexating agents. The metal complexation stability constants of these polyampholytes are interpreted in the light of their structural differences, they show a four fold coordination with respect to the examined bivalent metal ions. Poly-.-propyleneglycine has also been incorpo
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tion. The racemic mixture of chiral enantiomers is optically inactive. The most common form of optical activity was first measured at a constant wavelength by the angle of rotation of linearly polarized light. More recently the measurements have been extended to the entire range of visible and attainable ultr978-94-009-9380-8978-94-009-9378-5
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Charged and Reactive Polymershttp://image.papertrans.cn/o/image/702737.jpg
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