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Titlebook: One-Dimensional Organometallic Materials; An Analysis of Elect M. C. Böhm Book 1987 Springer-Verlag Berlin Heidelberg 1987 ITIES.Ion.cobalt

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书目名称One-Dimensional Organometallic Materials
副标题An Analysis of Elect
编辑M. C. Böhm
视频video
丛书名称Lecture Notes in Chemistry
图书封面Titlebook: One-Dimensional Organometallic Materials; An Analysis of Elect M. C. Böhm Book 1987 Springer-Verlag Berlin Heidelberg 1987 ITIES.Ion.cobalt
描述This lecture note gives an analysis of electronic structure effects for a new class of molecular solids, i. e. one-dimensional organometal­ lic systems formed by transition-met. l atoms that are embedded in a matrix of macrocyclic organic ligands. These systems as well as orga­ nic metals have focused considerable interest due to the potential formation of high-mobility charge carriers. For the present author it is difficult to participate in this restriction on a single physical property (i. e. high electronic conductivities, technical applications, etc. ). The lecture note is hopefully a small contribution to enhance the general understanding of certain electronic properties in organo­ metallic polymers. Those problems have been considered in the first place that seem to form a theoretical deficit in one specific field of solid-state chemistry. For the reader it will become evident that this contribution is a compromise always guided and limited by boundaries: i) An attempt to present problems to a ·chemical· audience which have their roots in solid-state physics. ii) The model calculations are limited by the currently available computational facilities. This ·boundary· implies t
出版日期Book 1987
关键词ITIES; Ion; cobalt; material; metallic materials; metals; nickel; solid-state chemistry
版次1
doihttps://doi.org/10.1007/978-3-642-93351-6
isbn_softcover978-3-540-17216-1
isbn_ebook978-3-642-93351-6Series ISSN 0342-4901 Series E-ISSN 2192-6603
issn_series 0342-4901
copyrightSpringer-Verlag Berlin Heidelberg 1987
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Electric Conductivities of Partially Oxidized Organometallic 1D Systemsems. Furthermore we give a short comparison of charge carrier parameters (i.e. mean free paths) of organometallic systems with quantities derived for organic metals and “inorganic” 1D conductors (i.e. Krogmann’s salt). Only simple phenomenological relations and qualitative interpretations are employ
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Neighborstrand Interactions in One-Dimensional Tight-Binding Models. The (Tetrathiosquarato)nickel(Ionductivities [IV.1–IV.3]. Recent numerical studies on the significance of higher dimensionalities in donor-acceptor systems are either based on one-electron calculations of the Wolfsberg-Helmholtz (WH) type [IV.4, IV.5] or on physically transparent phenomenological model Hamiltonians which can be t
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The Band Structure of the One-Dimensional (Bisglyoximato)Ni(II) Systemacteristic for semiconducting solids. The relevant experimental quantities are neither a function of the transition-metal center (Ni or Pd) nor a function of the halide sites (Br or I). The predominant halide component in Ni(gly)I is I.; the fractional oxidation state in the 1D column is thus +0.2.
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Introduction and Historical Reviewimental and theoretical interest over the past years [I.1–I.13]. 1D materials with building principles that differ from those realized in “classical” solids have been studied in many chemical and physical laboratories. Research fields in chemistry cover the synthesis and determination of crystal str
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