Titlebook: On-Surface Synthesis; Proceedings of the I André Gourdon Conference proceedings 2016 Springer International Publishing AG, part of Springer

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Bottom-Up Fabrication of Two-Dimensional Polymers on Solid Surfaces,mising and versatile synthetic approach is the bottom-up fabrication by polymerization of monomers into covalently cross-linked nanostructures on solid surfaces. This chapter introduces the synthetic approach consisting of monomer deposition and activation, and describes a typical characterization s

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Synthesis of Atomically Precise Graphene-Based Nanostructures: A Simulation Point of View, surfaces. After a brief introduction to the field, we review the state of the art of relevant computational methods. We then proceed by example through questions related to adsorption and diffusion, reactions and electronic structure, indicating both the strengths and limitations of computational a

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On-Surfaces Synthesis on Insulating Substrates,faces. Albeit, insulating surfaces pose several challenges for on-surface synthesis. First, many prototypical insulating support materials interact only weakly with organic molecules. This weak binding frequently results in molecule desorption rather than reaction activation when thermally initiatin

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Bottom-Up Fabrication of Two-Dimensional Polymers on Solid Surfaces,mplications when classical reactions are transferred from a beaker to a solid surface. The most important distinction is whether coupling proceeds irreversibly and remains kinetically controlled or whether thermodynamical control is possible. Ullmann coupling is a prominent example for an irreversib

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Formation Mechanisms of Covalent Nanostructures from Density Functional Theory, different process where molecules initially couple before undergoing a dehydrogenation step. The theory of the mechanism behind this coupling strategy is less developed than that of the on-surface Ullmann coupling, where fundamental questions remain to be unraveled. For example, by the subtle chang

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J. Michael Gottfriedigende Anzahl an Arbeitsplätzen durch Digitalisierung und Robotisierung gefährdet sind. Die Reihe „Fit for future“ beschäftigt sich eingehend mit dieser Thematik und978-3-658-27238-8978-3-658-27239-5Series ISSN 2730-6941 Series E-ISSN 2730-695X

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