Titlebook: Novel Selenium-Mediated Rearrangements and Cyclisations; Sohail Anjum Shahzad Book 2013 Springer-Verlag Berlin Heidelberg 2013 Benzoflueor

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Novel Selenium-Mediated Rearrangements and Cyclisations978-3-642-33173-2Series ISSN 2190-5053 Series E-ISSN 2190-5061

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The Synthesis of Naphthalenes and Biaryls,towards the synthesis of biaryl and naphthalene derivatives. The reactions of a range of .-keto ester substituted stilbenes with phenylselenenyl chloride and several Lewis acids are described, obtaining biaryls in good to excellent yields.

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Sohail Anjum ShahzadNominated by the University of Cardiff as an outstanding PhD thesis.Careful investigation of carbon nucleophiles in selenocyclizations.Description and development of excellent new synthetic routes.Inc

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General Introduction on Selenium,Selenium was discovered by Jöns Jacob Berzelius, a Swedish chemist, in the year 1817. He believed the element that was contaminating the sulphuric acid being produced at a factory in Sweden was tellurium. He realised he had found a new element. Berzelius suggested naming the element selenium; from the Greek word . for “moon”.

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2190-5053 iption and development of excellent new synthetic routes.IncIn his thesis, Sohail Shahzad carefully investigates carbon nucleophiles in selenocyclisations, as well as reaction protocols for performing such reactions catalytically. After a comprehensive introduction to the element selenium, the autho

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Book 2013tions catalytically. After a comprehensive introduction to the element selenium, the author goes on to report the synthesis of several substrates for carbocyclisation reactions and the use of selenium reagents for the preparation of dihydronaphthalenes. Further chapters detail electrophilic selenium

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Book 2013convert stilbene carbosylic acids into the corresponding isocoumarins. This thesis outlines some excellent new synthetic routes which will be useful tools for synthetic organic chemistry in the future.