Titlebook: Nitrogen Fixation; Yoshiaki Nishibayashi Book 2017 Springer International Publishing AG 2017 Dinitrogen Complexes.Sulfur-Supported Iron Co

Narrative

Determining and Understanding N-H Bond Strengths in Synthetic Nitrogen Fixation Cycles,chemistry. New approaches to this problem may offer more energy-efficient and carbon-neutral routes to this important industrial compound. Despite the ubiquity of ammine, amide, imide and diazenide ligands in coordination chemistry, little thermodynamic data is available for understanding N-H bond s

CHOKE

Dinitrogen Fixation by Transition Metal Hydride Complexes,mplexes can incorporate dinitrogen, but they are usually difficult to induce N–N bond cleavage. In contrast, multimetallic hydride complexes can split and hydrogenate dinitrogen through cooperation of the multiple metal hydrides. In this transformation, the hydride ligands serve as the source of bot

不近人情

,Functionalization of N2 by Mid to Late Transition Metals via N–N Bond Cleavage,ansition metal complexes. The relationships of electronic and structural parameters for the most common N.-bonding modes (end-on and side-on bridging) with N.-splitting reactivity are discussed. This analysis points towards electronic configurations with π. (end-on) and π.δ. (side-on) electrons with

参考书目

Synthetic Nitrogen Fixation with Mononuclear Molybdenum(0) Phosphine Complexes: Occupying the ,-Posent to catalytically convert N. to ammonia. In the framework of this research area, we have prepared complexes of the type [Mo(N.)(PEP)(P.)] (E = N, P; P. = dppm, dmpm) in which the linear PEP ligand coordinates in a facial geometry. Similar complexes have been prepared using mixed carbene–phosphine