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Titlebook: New Macromolecular Architecture and Functions; Proceedings of the O Mikiharu Kamachi,Akira Nakamura Conference proceedings 1996 Springer-Ve

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Stereospecific Living Polymerization of Methacrylate with Binary Initiator Systems,, all of which utilize binary initiator systems comprising bulky anionic initiator and Lewis acid; the latter works as stereo specificity modifier. Particular emphasis is placed on the unique synthetic utility of bulky aluminum phenoxides in methacrylate polymerization; heterotactic polymerization o
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Non-Conjugated and Conjugated Dienes in Acyclic Diene Metathesis (ADMET) Chemistry, (ROMP) as a means to produce a variety of polymers via metal exchange reactions. ADMET chemistry is not a new concept, although it had been unsuccessful for a period of more than 20 years. The realization that the acidity of the catalyst influences the polymerization reaction led to the development
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Polyethyleneimine Derivatives as Nucleic Acid Model and Interaction with DNA,. The polymers were found to interact with DNA accompanied by induction of conformational change. The induced conformation of DNA by interaction with the polymer containing uracil and homoserine (PEI-Hse-Ura) was concluded as super triple helical structure. The formation of the polymer complex, DNA:
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The Dendritic Box; Synthesis, Properties, and Applications,henylalanine groups. This so-called dendritic box has a diameter of approximately 4.5 nm, as determined by DLS and SAXS, and has internal cavities which can be used for the encapsulation of guest molecules. Supramolecular encapsulation is achieved by performing the construction of the box in the pre
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New Macromolecular Architectures and Functions Through Macromolecular Recognition by Cyclodextrins,inyl ether) (PMVE), and poly(oxytrimethylene) (POT) to give crystalline compounds in high yields. The complex formation is highly selective. α-CD formed complexes with PEG and POT, although it did not form complexes with PPG and PMVE. γ-CD formed complexes with PMVE, although α- and β-CD did not for
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Novel Unimolecular Micelles of Hydrophobically Modified Polyelectrolytes: Synthesis, Characterizatitructures such as cyclododecyl (Cd), adamantyl (Ad), and 1-naphthyl (1-Np) groups undergo intrapolymer self-organization in aqueous solution and form unimolecular micelles (unimers) independent of the polymer concentrations. These unimers are highly compact as indicated by light scattering and NMR r
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