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Titlebook: Near-critical and Supercritical Water and Their Applications for Biorefineries; Zhen Fang,Chunbao (Charles) Xu Book 2014 Springer Science+

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Hydrogen Bonding in Supercritical Watere structural and dynamic properties of SCW and its capacity as a solvent. In order to deal with the HB it is necessary to have definite criteria that specify when a hydrogen bond exists or not, and these are provided. The extent of HB in SCW is expressed by means of the mean number of hydrogen bonds
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Thermodynamic Analysis of the Supercritical Water Gasification of Biomassasification (SCWG) process. A thermodynamic equilibrium model allows calculating which is the system composition at equilibrium. Equilibrium composition can allow calculating, with good approximation, the overall process yields, especially when high temperatures and/or catalysts are used. In this Ch
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Optical Reactors for Microscopic Visualization of Chemical Processes in Sub- and Supercritical Water of aqueous systems significantly differ from those at ambient conditions due to largely different properties of water under such extreme conditions. This chapter mainly reviews flow-through optical reactors that are designed to allow microscopic observations of chemical processes in sub- and superc
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Fused Silica Capillary Reactor and Its Applicationsoth ends sealed by fusion in an oxyhydrogen flame after the sample in solid, liquid, or gaseous form (or their mixtures) was loaded. The fused silica is stable in aqueous solutions with low pH and the FSCR can hold 100 MPa internal pressure or slightly higher. Two types of customer-designed heating-
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Production of Renewable Solid Fuel Hydrochar from Waste Biomass by Sub- and Supercritical Water Treacounters serious problems in existing power plants. This chapter discusses sub- and supercritical water treatment (SSCWT) to upgrade biomass feedstocks, and presents a systematic characterization of fuel properties of the resultant hydrochars. Hydrochars from SSCWT of biomass have significantly impr
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Supercritical Water Oxidation (SCWO) for Wastewater Treatmentce with the self-dissociation of water at near-critical and above supercritical (T. = 374 °C, P. = 22.1 MPa) conditions. Therefore, supercritical water is considered both as a solvent for organic materials and as a reactant at processes such as the oxidative treatment of wastewaters, the gasificatio
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