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Titlebook: Name Reactions; A Collection of Deta Jie Jack Li Textbook 20094th edition Springer-Verlag Berlin Heidelberg 2009 Amino acid.Claisen rearran

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书目名称Name Reactions
副标题A Collection of Deta
编辑Jie Jack Li
视频video
概述Many chemists collect named and unnamed reactions and their mechanisms.Will make this time-consuming effort redundant.Gives the earliest and latest references to these name reactions.Gives representat
图书封面Titlebook: Name Reactions; A Collection of Deta Jie Jack Li Textbook 20094th edition Springer-Verlag Berlin Heidelberg 2009 Amino acid.Claisen rearran
描述I don‘t have my name on anything that I don‘t really do. –Heidi Klum Can the organic chemists associated with so-called “Named Reactions” make the same claim as supermodel Heidi Klum? Many scholars of chemistry do not hesitate to point out that the names associated with “name reactions” are often not the actual inventors. For instance, the Arndt–Eistert reaction has nothing to do with either Arndt or Eistert, Pummerer did not discover the “Pummerer” rearrangement, and even the famous Birch reduction owes its initial discovery to someone named Charles Wooster (first reported in a DuPont patent). The list goes on and on… But does that mean we should ignore, boycott, or outlaw “named reactions”? Absolutely not. The above examples are merely exceptions to the rule. In fact, the chemists associated with name reactions are typically the original discoverers, contribute greatly to its general use, and/or are the first to popularize the transformation. Regardless of the controversial history underlying certain named reactions, it is the students of organic chemistry who benefit the most from the cataloging of reactions by name. Indeed, it is with education in mind that Dr. Jack Li has mast
出版日期Textbook 20094th edition
关键词Amino acid; Claisen rearrangement; Coupling reaction; Cycloaddition; Ene reaction; Overman rearrangement;
版次4
doihttps://doi.org/10.1007/978-3-642-01053-8
isbn_ebook978-3-642-01053-8
copyrightSpringer-Verlag Berlin Heidelberg 2009
The information of publication is updating

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Springer-Verlag Berlin Heidelberg 2009
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,Arndt—Eistert homologation,One-carbon homologation of carboxylic acids using diazomethane.
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,Baeyer–Villiger oxidation,The most electron-rich alkyl group (more substituted carbon) migrates first. The general migration order: tertiary alkyl > cyclohexyl > secondary alkyl > benzyl > phenyl > primary alkyl > methyl >> H.
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