| 书目名称 | Multifunctional Molecular Magnets Based on Octacyanidometalates |
| 编辑 | Kenta Imoto |
| 视频video | |
| 概述 | Nominated by The University of Tokyo as an outstanding Ph.D. thesis.Demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies.Includes numerous step-by-step tutorials to help |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for noveloptical switching devices.. |
| 出版日期 | Book 2017 |
| 关键词 | Spin-crossover Phenomenon; Photo-induced Magneitzation; Ionic Conductivity; Cyanido-bridged Metal Assem |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-981-10-6135-6 |
| isbn_softcover | 978-981-13-5577-6 |
| isbn_ebook | 978-981-10-6135-6Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |
发表于 2025-3-21 20:04:42
